Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate
| Autor: | J. Derek Woollins, Alexandra M. Z. Slawin, Louise M. Diamond |
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| Rok vydání: | 2014 |
| Předmět: |
crystal structure
Crystallography biology Acenaphthene chemistry.chemical_element Atom (order theory) Methane sulfonate General Chemistry Crystal structure Condensed Matter Physics Bioinformatics biology.organism_classification Medicinal chemistry Data Reports acenaphthene chemistry.chemical_compound chemistry QD901-999 tellurium triflate Tetra General Materials Science Tellurium Trifluoromethanesulfonate Deca |
| Zdroj: | Acta Crystallographica Section E: Structure Reports Acta Crystallographica Section E, Vol 70, Iss 9, Pp o1003-o1004 (2014) |
| ISSN: | 1600-5368 |
| DOI: | 10.1107/s1600536814018170 |
| Popis: | In the title compound, C18H13Te2+·CF3O3S−, the TeIIatom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te—Te—O system, with a Te—Te—O angle of 172.3 (1)° and a Te—O distance of 2.816 (5) Å, which may suggest the presence of a three-centre–four-electron (3c–4e) bond. Secondary Te...O interactions [3.003 (4) and 3.016 (4) Å], involving the second TeIIatom of the binuclear molecule, are also noted, resulting in a supramolecular layer in thebcplane. |
| Databáze: | OpenAIRE |
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