Operando magnetic resonance: monitoring the evolution of conversion and product distribution during the heterogeneous catalytic ethene oligomerisation reaction
| Autor: | Lynn F. Gladden, S. Tegan Roberts, Andrew J. Sederman, Michal Lutecki, Matthew P. Renshaw, Mick D. Mantle, James McGregor |
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| Rok vydání: | 2013 |
| Předmět: |
010405 organic chemistry
Chemistry Metals and Alloys Analytical chemistry General Chemistry 010402 general chemistry 01 natural sciences Catalysis Product distribution 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Materials Chemistry Ceramics and Composites Spectroscopy |
| Zdroj: | Chemical communications (Cambridge, England). 49(89) |
| ISSN: | 1364-548X |
| Popis: | Operando magnetic resonance (MR) spectroscopy has been used to follow an ethene oligomerisation reaction performed at 110 °C, 28 barg over a 1 wt% Ni/SiO2–Al2O3 catalyst. Spectra acquired over the timecourse of the reaction allow the calculation of conversion and product distribution as a function of time-on-stream. |
| Databáze: | OpenAIRE |
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