Synthesis of a series of M(II) (M = Mn, Fe, Co) chloride complexes with both inter- and intra-ligand hydrogen bonding interactions

Autor:	Michael J. Drummond, Alison R. Fout, Clare A. Leahy, Josh Vura-Weis
Rok vydání:	2021
Předmět:	Inorganic Chemistry Metal chloride Metal Crystallography Chemistry Ligand Hydrogen bond visual_art medicine visual_art.visual_art_medium Chloride medicine.drug
Zdroj:	Dalton transactions (Cambridge, England : 2003). 50(35)
ISSN:	1477-9234
Popis:	Hydrogen bonding networks are vital for metallo-enzymes to function; however, modeling these systems is non-trivial. We report the synthesis of metal chloride (M = Mn, Fe, Co) complexes with intra- and inter-ligand hydrogen bonding interactions. The intra-ligand hydrogen bonds are shown to have a profound effect on the geometry of the metal center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::920c4f48b484f89a9150756bf6942600 https://pubmed.ncbi.nlm.nih.gov/34519757 Zobrazit plný text záznamu