Hydrogen-bonded chains in threecis-dichloridoplatinum(II) complexes bearing piperidine and amine ligands
| Autor: | Luc Van Meervelt, Ngan Nguyen Bich, Chi Nguyen Thi Thanh |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Organoplatinum Compounds
Hydrogen Ligand Hydrogen bond Stereochemistry Stacking chemistry.chemical_element Hydrogen Bonding Crystal structure Crystallography X-Ray Ligands Condensed Matter Physics Inorganic Chemistry Crystal Crystallography chemistry.chemical_compound Piperidines chemistry Materials Chemistry Piperidine Amines Physical and Theoretical Chemistry Platinum |
| Zdroj: | Acta Crystallographica Section C Structural Chemistry. 70:297-301 |
| ISSN: | 2053-2296 |
| Popis: | The crystal structures ofcis-dichlorido(ethylamine-κN)(piperidine-κN)platinum(II), [PtCl2(C2H7N)(C5H11N)], (I),cis-dichlorido(3-methoxyaniline-κN)(piperidine-κN)platinum(II), [PtCl2(C5H11N)(C7H9NO)], (II), andcis-dichlorido(piperidine-κN)(quinoline-κN)platinum(II), [PtCl2(C5H11N)(C9H7N)], (III), have been determined at 100 K in order to verify the influence of the nonpiperidine ligand on the geometry and crystal packing. The crystal packing is characterized by N—H...Cl hydrogen bonding, resulting in the formation of chains of molecules connected in a head-to-tail fashion. Hydrogen-bonding interactions play a major role in the packing of (I), where the chains further aggregate into planes, but less so in the case of (II) and (III), where π–π stacking interactions are of greater importance. |
| Databáze: | OpenAIRE |
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