Synthesis of the Small Pore Silicoaluminophosphate STA-6 by Using Supramolecular Self-Assembled Organic Structure Directing Agents
| Autor: | Avelino Corma, Manuel Moliner, Raquel Martínez-Franco, Ángel Cantín |
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| Rok vydání: | 2014 |
| Předmět: |
Materials science
Silicon General Chemical Engineering Supramolecular chemistry chemistry.chemical_element MOLECULAR-SIEVES Molecular sieve AZAMACROCYCLE Catalysis law.invention ZEOLITE SYNTHESIS chemistry.chemical_compound QUIMICA ORGANICA law Materials Chemistry Organic chemistry Molecule Crystallization OLEFINS METALLOALUMINOPHOSPHATES STA-6 CATALYST General Chemistry CONVERSION Monomer OPEN-FRAMEWORK MATERIALS chemistry Chemical engineering Organic structure METHANOL CRYSTALLIZATION |
| Zdroj: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia instname |
| ISSN: | 1520-5002 0897-4756 |
| DOI: | 10.1021/cm5005483 |
| Popis: | By means of organic structure directing agents (OSDA) formed by bulky paired quinolinium derived molecules, obtained by self-assembled monomers, it has been possible to synthesize for the first time the pure silicoaluminophosphate form of the small pore STA-6 zeotype. This synthesis method allows obtaining samples with very well dispersed framework silicon atoms, opening the possibility for its use in catalysis. This work has been supported by the Spanish Government through Consolider Ingenio 2010-Multicat, the "SEVERO OCHOA PROGRAM", MAT2012-37160 and, Intramural-201480I015. Manuel Moliner also acknowledges to "Sub-programa Ramon y Cajal" for the contract RYC-2011-08972. |
| Databáze: | OpenAIRE |
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