Interplay of unique N⋯π pnicogen and H⋯π/H⋯O hydrogen bonding interactions in the heterodimers of nitromethane with acetylene and benzene as π-electron donors: experimental characterization at low temperatures under isolated conditions with computational corroboration

Autor:	Nandalal Mahapatra, Swaroop Chandra, N. Ramanathan, K. Sundararajan
Rok vydání:	2022
Předmět:	Acetylene Polymers Temperature General Physics and Astronomy Benzene Hydrogen Bonding Electrons Physical and Theoretical Chemistry
Zdroj:	Physical chemistry chemical physics : PCCP. 24(46)
ISSN:	1463-9084
Popis:	The existence of unique ON⋯π pnicogen bonding in combination with C-H⋯π/C-H⋯O hydrogen bonding interactions has been experimentally affirmed in the heterodimers of nitromethane with aliphatic (acetylene; NMAc) and aromatic (benzene; NMBz) π-electron donors at low temperatures under isolated conditions. The potential energy surfaces of NMAc and NMBz dimers have been probed for stationary points using
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::91091ac6ff0c5bf3f927fcd9415de0f4 https://pubmed.ncbi.nlm.nih.gov/36398764 Zobrazit plný text záznamu