SYNTHESIS OF HALOGEN DERIVATIVES OF N-ARYLAMINOCARBONYL-1,4-BENZOQUINONE MONOIMINES
| Autor: | E. N. Lysenko, A. P. Avdeenko, S. A. Konovalova |
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| Rok vydání: | 2017 |
| Předmět: | |
| Zdroj: | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ, Vol 22, Iss 1(61), Pp 103-118 (2017) |
| ISSN: | 2414-5963 2304-0947 |
| DOI: | 10.18524/2304-0947.2017.1(61).94716 |
| Popis: | The hydrohalogenation of N-arylaminocarbonyl-1,4-benzoquinone monoimines is optimal method to obtain the halogenated derivatives. This method allows obtaining the pure products in high yield with a halogen atom in the aminophenol ring. The bromination of N-arylaminocarbonyl-1,4-benzoquinone monoimines and their reduced forms allows obtaining of individual products only in several cases. The bromination allows synthesizing of products with a halogen atom not only in the aminophenol ring, but in the aryl moiety too. As a result of the experiment we have found the optimal conditions to synthesis the N-arylaminocarbonyl-1,4-benzoquinone monoimine derivatives containing halogen atom. The bromination and hydrohalogenation products with one free ortho-position toward to the imine carbon atom of the quinoid ring can be used as synthons in the synthesis of heterocyclic compounds – 1,3-benzoxazole derivatives. |
| Databáze: | OpenAIRE |
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