Exploiting dense shell/packing principles to invoke stereoselectivity in a reaction accelerated by a chiral dendrimer
| Autor: | Adam Ellis, Lance J. Twyman, Melanie Wallace |
|---|---|
| Rok vydání: | 2013 |
| Předmět: |
Dendrimers
Materials science Stereochemistry Metals and Alloys Shell (structure) Molecular Conformation Substrate (chemistry) Stereoisomerism General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Chemical physics Dendrimer Materials Chemistry Ceramics and Composites Reactivity (chemistry) Stereoselectivity Amines Layer (electronics) |
| Zdroj: | Chemical communications (Cambridge, England). 49(73) |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | As dendrimers approach their dense shell or dense packed limit, a\ud certain amount of conformational organization exists. Any substrate\ud binding within the dendrimer’s external layerwill experience the same\ud organizational effects. This paper describes how these effects can be\ud exploited towards stereocontrol with respect to binding and reactivity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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