Toward Improved Charge Separation through Conformational Control in Copper Coordination Complexes

Autor:	Paul J. Griffin, Bronte J. Charette, John H. Burke, Josh Vura-Weis, Richard D. Schaller, David J. Gosztola, Lisa Olshansky
Rok vydání:	2022
Předmět:	Colloid and Surface Chemistry Coordination Complexes Electron Spin Resonance Spectroscopy Molecular Conformation General Chemistry Ligands Biochemistry Copper Catalysis
Zdroj:	Journal of the American Chemical Society. 144:12116-12126
ISSN:	1520-5126 0002-7863
Popis:	The continued development of solar energy as a renewable resource necessitates new approaches to sustaining photodriven charge separation (CS). We present a bioinspired approach in which photoinduced conformational rearrangements at a ligand are translated into changes in coordination geometry and environment about a bound metal ion. Taking advantage of the differential coordination properties of Cu
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::90b9d48ccac8c80ca5b5a6dfc079e8d6 https://doi.org/10.1021/jacs.2c02580 Zobrazit plný text záznamu