Cyclization of Pyrene Oligomers: Cyclohexa-1,3-pyrenylene

Autor: Teresa M. Figueira-Duarte, Martin Baumgarten, Manfred Wagner, Ashok Keerthi, Dominik Lorbach, Klaus Müllen
Rok vydání: 2015
Předmět:
Zdroj: Angewandte Chemie International Edition. 55:418-421
ISSN: 1433-7851
DOI: 10.1002/anie.201508180
Popis: First synthesis of the macrocycle cyclohexa(1,3-pyrenylene) is achieved in six steps starting with pyrene, leading to a non-aggregating highly twisted blue-light-emitting material. The cyclodehydrogenation of the macrocycle offers a promising synthesis route to holey-nanographene.
Databáze: OpenAIRE