Cyclization of Pyrene Oligomers: Cyclohexa-1,3-pyrenylene
Autor: | Teresa M. Figueira-Duarte, Martin Baumgarten, Manfred Wagner, Ashok Keerthi, Dominik Lorbach, Klaus Müllen |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Angewandte Chemie International Edition. 55:418-421 |
ISSN: | 1433-7851 |
DOI: | 10.1002/anie.201508180 |
Popis: | First synthesis of the macrocycle cyclohexa(1,3-pyrenylene) is achieved in six steps starting with pyrene, leading to a non-aggregating highly twisted blue-light-emitting material. The cyclodehydrogenation of the macrocycle offers a promising synthesis route to holey-nanographene. |
Databáze: | OpenAIRE |
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