Fabrication and centeracterization of ordered CuIn(1−x)Ga x Se2 nanopore films via template-based electrodeposition

Autor: Maojun Zheng, Li Ma, Tao Zhou, Ming‐ming Li, Wenzhong Shen, Changli Li
Rok vydání: 2012
Předmět:
Zdroj: Nanoscale Research Letters
ISSN: 1556-276X
DOI: 10.1186/1556-276x-7-675
Popis: Ordered CuIn(1−x)Ga x Se2 (CIGS) nanopore films were prepared by one-step electrodeposition based on porous anodized aluminum oxide templates. The as-grown film shows a highly ordered morphology that reproduces the surface pattern of the substrate. Raman spectroscopy and X-ray diffraction pattern show that CIGS nanopore films had ideal chalcopyrite crystallization. Energy dispersive spectroscopy reveals the Cu-Se phases firstly formed in initial stage of growth. Then, indium and gallium were incorporated in the nanopore films in succession. Cu-Se phase is most likely to act as a growth promoter in the growth progress of CIGS nanopore films. Due to the high surface area and porous structure, this kind of CIGS films could have potential application in light-trapping CIGS solar cells and photoelectrochemical water splitting.
Databáze: OpenAIRE