Electrochemical collective synthesis of labeled pyrroloindoline alkaloids with Freon-type methanes as functional C1 synthons

Autor:	Chao Chen, Ru-Xin Liu, Feng Xiong, Zi-Hao Li, Jun-Chen Kang, Tong-Mei Ding, Shu-Yu Zhang
Rok vydání:	2022
Předmět:	Alkaloids Materials Chemistry Metals and Alloys Ceramics and Composites Stereoisomerism General Chemistry Chlorofluorocarbons Methane Catalysis Oxindoles Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:9230-9233
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc03301a
Popis:	Utilization of Freon-type methanes as functional one-carbon synthons in the synthesis of various deuterated indoline alkaloids was demonstrated here. A series of halomethyl radicals were generated from electro-reductive C-X cleavage of Freon-type methanes and captured efficiently by acrylamides to provide various halogenated oxindoles
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::902d93a5f3d0faf98c36a8cb21c3fbe9 https://doi.org/10.1039/d2cc03301a Zobrazit plný text záznamu