Prospects of Value‐Added Chemicals and Hydrogen via Electrolysis
| Autor: | Corina Andronescu, Batyr Garlyyev, Song Xue, Aliaksandr S. Bandarenka, Johannes Fichtner |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
Hydrogen Electrolytic cell General Chemical Engineering Chemie chemistry.chemical_element electrooxidation 02 engineering and technology Electrolyte peroxide production 010402 general chemistry Electrosynthesis 01 natural sciences law.invention alcohols electrosynthesis law Very Important Paper electrolysis Environmental Chemistry General Materials Science Hydrogen production Electrolysis Electrolysis of water Minireviews 021001 nanoscience & nanotechnology ddc 0104 chemical sciences Anode General Energy chemistry Chemical engineering Minireview 0210 nano-technology |
| Zdroj: | Chemsuschem |
| ISSN: | 1864-564X 1864-5631 |
| Popis: | Cost is a major drawback that limits the industrial‐scale hydrogen production through water electrolysis. The overall cost of this technology can be decreased by coupling the electrosynthesis of value‐added chemicals at the anode side with electrolytic hydrogen generation at the cathode. This Minireview provides a directory of anodic oxidation reactions that can be combined with cathodic hydrogen generation. The important parameters for selecting the anodic reactions, such as choice of catalyst material and its selectivity towards specific products are elaborated in detail. Furthermore, various novel electrolysis cell architectures for effortless separation of value‐added products from hydrogen gas are described. An ode to cheapness: This Minireview focuses on the aspects of making the electrolytic hydrogen production more cost efficient. Several anodic oxidation reactions with value‐added products are reviewed that can replace the anodic oxygen evolution reaction. The choice of electrocatalysts, increasing reaction selectivity as well as possible cell architectures are elaborated in detail. |
| Databáze: | OpenAIRE |
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