Surfactant-free carnauba wax dispersion and its use for layer-by-layer assembled protective surface coatings on wood
| Autor: | Benjamin Michen, Ingo Burgert, Alina Lozhechnikova, Monika Österberg, Herve Bellanger |
|---|---|
| Přispěvatelé: | Department of Forest Products Technology, Swiss Federal Laboratories for Materials Science and Technology, Department of Bioproducts and Biosystems, Aalto-yliopisto, Aalto University |
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Carnauba wax Hydrophobicity General Physics and Astronomy Nanoparticle 02 engineering and technology engineering.material 010402 general chemistry 01 natural sciences chemistry.chemical_compound Moisture buffering Coating Composite material ta216 Wax Moisture Wood modification Surfaces and Interfaces General Chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences Surfaces Coatings and Films chemistry UV resistance visual_art ZnO visual_art.visual_art_medium engineering Particle Particle size 0210 nano-technology Dispersion (chemistry) |
| Zdroj: | Applied Surface Science. 396:1273-1281 |
| ISSN: | 0169-4332 |
| Popis: | Protection from liquid water and UV radiation are equally important, and a sophisticated approach is needed when developing surface coatings that preserve the natural and well-appreciated aesthetic appearance of wood. In order to prevent degradation and prolong the service life of timber, a protective coating was assembled using carnauba wax particles and zinc oxide nanoparticles via layer-by-layer deposition in water. For this purpose, a facile sonication route was developed to produce aqueous wax dispersion without any surfactants or stabilizers. The suspension was stable above pH 4 due to the electrostatic repulsion between the negatively charged wax particles. The particle size could be controlled by the initial wax concentration with average particle sizes ranging from 260 to 360 nm for 1 and 10 g/L, respectively. The deposition of wax particles onto the surface of spruce wood introduced additional roughness to the wood surface at micron level, while zinc oxide provided nano roughness and UV-absorbing properties. In addition to making wood superhydrophobic, this novel multilayer coating enhanced the natural moisture buffering capability of spruce. Moreover, wood surfaces prepared in this fashion showed a significant reduction in color change after exposure to UV light. A degradation of the wax through photocatalytic activity of the ZnO particles was measured by FTIR, indicating that further studies are required to achieve long-term stability. Nevertheless, the developed coating showed a unique combination of superhydrophobicity and excellent moisture buffering ability and some UV protection, all achieved using an environmentally friendly coating process, which is beneficial to retain the natural appearance of wood and improve indoor air quality and comfort. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect