Structural and Bonding Analysis in Monomeric Actinide(IV) Oxalate from Th(IV) to Pu(IV): Comparison with the An(IV) Nitrate Series

Autor: Christelle Tamain, Matthieu Autillo, Dominique Guillaumont, Laetitia Guérin, Richard E. Wilson, Claude Berthon
Rok vydání: 2022
Předmět:
Zdroj: Inorganic Chemistry. 61:12337-12348
ISSN: 1520-510X
0020-1669
DOI: 10.1021/acs.inorgchem.2c01674
Popis: Single-crystal X-ray diffraction (SC-XRD) structures and Raman spectra of a series of new isomorphous molecular An(IV)-oxalate compounds (Th, U, Np, and Pu) are reported. These complexes are crystallized with cobalt(III) hexamine ([Co(NH
Databáze: OpenAIRE