Nitrogen interactions at metal surfaces
Autor: | Aart W. Kleyn, Michael A. Gleeson |
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Přispěvatelé: | S&C overig (HIMS, FNWI) |
Rok vydání: | 2013 |
Předmět: |
Condensed Matter::Quantum Gases
Nuclear and High Energy Physics Passivation Chemistry Energy transfer chemistry.chemical_element Nitrogen Metal Adsorption Low-energy ion scattering Chemical physics visual_art Translational energy Physics::Atomic and Molecular Clusters visual_art.visual_art_medium Physics::Atomic Physics Atomic physics Instrumentation Molecular beam |
Zdroj: | Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 317, 109-114 Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms, 317(Part A), 109-114. Elsevier |
ISSN: | 0168-583X |
DOI: | 10.1016/j.nimb.2013.02.005 |
Popis: | Molecular beam experiments with specially prepared beams allow the study of the interaction of very reactive species with surfaces. In the present case the interaction of N-atoms with Ag(1 1 1) is studied. The energy of the atoms is around 5 eV, precisely between the classical energy regimes of seeded molecular beams and low energy ion scattering. We will show evidence that the electronic state of the incident atoms is very important in the interaction. The systems studied experimentally have also been investigated by theoretical modeling. Comparisons between theory and experiment will be discussed. We will consider if N-atoms can lead to a passive adlayer that is not reactive to subsequent N-atoms. It appears unlikely, which may be a consequence of incident N-atoms can removing adsorbed N-atoms in an Eley–Rideal reaction. |
Databáze: | OpenAIRE |
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