Disc antenna enhanced infrared spectroscopy: From felf-assembled monolayers to membrane proteins

Autor: Ramona Schlesinger, Kenichi Ataka, Hirofumi Seki, Joachim Heberle, Emanuel Pfitzner
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Rhodopsin
Materials science
nanostencil lithography
Infrared spectroscopy
Bioengineering
02 engineering and technology
Biosensing Techniques
010402 general chemistry
01 natural sciences
Benzoates
retinal
Electrolytes
Monolayer
Spectroscopy
Fourier Transform Infrared

membrane protein
Sulfhydryl Compounds
surface-enhanced infrared absorption spectroscopy
Spectroscopy
Instrumentation
Plasmon
Fluid Flow and Transfer Processes
chemistry.chemical_classification
business.industry
Process Chemistry and Technology
Biomolecule
500 Naturwissenschaften und Mathematik::530 Physik::530 Physik
Sensory rhodopsin II
Membrane Proteins
Self-assembled monolayer
Hydrogen-Ion Concentration
FTIR difference spectroscopy
021001 nanoscience & nanotechnology
0104 chemical sciences
chemistry
self-assembled monolayer
Molecular vibration
Microscopy
Electron
Scanning

Optoelectronics
Gold
0210 nano-technology
business
Genetic Engineering
DOI: 10.1021/acssensors.8b00139
Popis: Plasmonic surfaces have emerged as a powerful platform for biomolecular sensing applications and can be designed to optimize the plasmonic resonance for probing molecular vibrations at utmost sensitivity. Here, we present a facile procedure to generate metallic microdisc antenna arrays that are employed in surface-enhanced infrared absorption (SEIRA) spectroscopy of biomolecules. Transmission electron microscopy (TEM) grids are used as shadow mask deployed during physical vapor deposition of gold. The resulting disc-shaped antennas exhibit enhancement factors of the vibrational bands of 4 × 104 giving rise to a detection limit
Databáze: OpenAIRE