Synthesis, Structures, and Properties of Neutral and Radical Cationic S,C,C-Bridged Triphenylamines
| Autor: | Chitoshi Kitamura, Taisuke Matsumoto, Seiji Tobita, Toshitada Yoshihara, Shin-ichiro Kato, Motoko S. Asano, Shuichi Suzuki, Takanori Matsuoka |
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| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Chemistry Organic Chemistry Cationic polymerization chemistry.chemical_element 010402 general chemistry Triphenylamine 01 natural sciences Biochemistry Sulfur 0104 chemical sciences Crystallography chemistry.chemical_compound Radical ion Physical and Theoretical Chemistry Spectroscopy Electronic properties |
| Zdroj: | Organic Letters. 22:734-738 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/acs.orglett.9b04575 |
| Popis: | A structurally constrained S,C,C-bridged triphenylamine was synthesized, and the corresponding radical cation was obtained as a hexachloroantimonate by chemical oxidation. An X-ray crystallographic analysis revealed an almost planar structure for this radical cation, which thus represents the first example of a planar, para-unsubstituted triphenylamine radical cation analogue with a sulfur bridge. The electronic properties of the radical cation were examined by UV–vis–NIR and ESR spectroscopy as well as DFT calculations. |
| Databáze: | OpenAIRE |
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