Electrochemical behaviour of selenoorganic compounds—I. Dibenzo (b,d) selenopyrane and related compounds
| Autor: | B. Dakova, L. Lamberts, M. Evers, Alain Walcarius |
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| Přispěvatelé: | Facultés Universitaires Notre Dame de la Paix (FUNDP), Rhône-Poulenc / Nattermann [Cologne Research Centre] |
| Rok vydání: | 1990 |
| Předmět: |
Reaction mechanism
General Chemical Engineering Inorganic chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Lithium perchlorate 0104 chemical sciences Coulometry chemistry.chemical_compound chemistry [CHIM.ANAL]Chemical Sciences/Analytical chemistry Cyclic voltammetry 0210 nano-technology Acetonitrile Platinum Voltammetry |
| Zdroj: | Electrochimica Acta Electrochimica Acta, Elsevier, 1990, 35 (11-12), pp.1855-1860. ⟨10.1016/0013-4686(90)87090-O⟩ |
| ISSN: | 0013-4686 |
| DOI: | 10.1016/0013-4686(90)87090-o |
| Popis: | International audience; The electrochemical properties of selenoxanthene, selenoxanthene-9-ol and selenoxanthone in non-aqueous and mixed media are investigated by voltammetry at rotating platinum and vitrous carbon disk electrodes, cyclic voltammetry, chronopotentiometry and constant potential coulometry. In “dry” acetonitrile selenoxanthene leads to selenoxanthylium cation. In the presence of water, selenoxanthene-9-ol is obtained. Further oxidation of selenoxanthene-9-ol gives the selenoxanthone which can be oxidized to the corresponding selenoxide. Influence of acids and bases is shown. |
| Databáze: | OpenAIRE |
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