Six-coordinate mononuclear dysprosium(iii) single-molecule magnets with the triphenylphosphine oxide ligand

Autor:	Kuduva R. Vignesh, Dimitris I. Alexandropoulos, Haomiao Xie, Kim R. Dunbar
Rok vydání:	2020
Předmět:	chemistry.chemical_classification Materials science Ligand Iodide chemistry.chemical_element Halide Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Octahedron Ab initio quantum chemistry methods Dysprosium Molecule Triphenylphosphine oxide
Zdroj:	Dalton Transactions. 49:4694-4698
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt00801j
Popis:	Structural, magnetic and theoretical studies of three octahedral mononuclear DyIII complexes with triphenylphosphine oxide and halide ligands are reported. The Cl- and Br- analogues exhibit SMM behavior with energy barriers of 49.1 K and 70.9 K, respectively under a small dc field. Ab initio calculations were performed, the results of which predict higher energy barriers for iodide containing SMMs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8ef7171f048896e060d22d2e34b6b5b2 https://doi.org/10.1039/d0dt00801j Zobrazit plný text záznamu