Playing with the weakest supramolecular interactions in a 3D crystalline hexakis[60]fullerene induces control over hydrogenation selectivity
| Autor: | Estefania Fernandez-Bartolome, Eider Rodríguez-Sánchez, Nazario Martín, Arturo Gamonal, José Santos, José Sánchez Costa, Saeed Khodabakhshi, E. Carolina Sañudo |
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| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Dipòsit Digital de la UB Universidad de Barcelona Chemical Science |
| Popis: | Weak forces can play an essential role in chemical reactions. Controlling such subtle forces in reorganization processes by applying thermal or chemical stimuli represents a novel synthetic strategy and one of the main targets in supramolecular chemistry. Actually, to separate the different supramolecular contributions to the stability of the 3D assemblies is still a major challenge. Therefore, a clear differentiation of these contributions would help in understanding the intrinsic nature as well as the chemical reactivity of supramolecular ensembles. In the present work, a controlled reorganization of an hexakis[60]fullerene-based molecular compound purely governed by the weakest van der Waals interactions known, i.e. the dihydrogen interaction – usually called sticky fingers – is illustrated. This pre-reorganization of the hexakis[60]fullerene under mild conditions allows a further selective hydrogenation of the crystalline material via hydrazine vapors exposure. This unique two-step transformation process is monitored by single-crystal to single-crystal diffraction (SCSC) which allows the direct observation of the molecular movements in the lattice and the subsequent solid–gas hydrogenation reaction. Weak forces play an essential role in chemistry. Controlling these supramolecular interactions will contribute to the creation dynamic absorbent materials with a variety of technological applications as chemosensors and environmental remediation. |
| Databáze: | OpenAIRE |
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