Anion templating from a silver(i ) dithiophosphate 1D polymer forming discrete cationic and neutral octa- and decanuclear silver(i ) clusters
| Autor: | Ching-Shiang Fang, Werner E. van Zyl, Yi-Juan Li, Hao-Wei Chang, Bijay Sarkar, Chen-Wei Liu, Jian-Hong Liao |
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| Rok vydání: | 2014 |
| Předmět: |
Magnetic Resonance Spectroscopy
Silver Polymers Hydride Ligand Coordination polymer Inorganic chemistry Cationic polymerization Crystallography X-Ray Phosphates Inorganic Chemistry chemistry.chemical_compound Crystallography Monomer chemistry Coordination Complexes Halogen Cluster (physics) Stoichiometry |
| Zdroj: | Dalton Trans.. 43:12380-12389 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c4dt00691g |
| Popis: | We report on a Ag5 coordination polymer and discrete Ag8 and Ag10 dithiophosphate clusters. The cluster formation and structures were affected by the stoichiometric control of the M : L molar ratios used. The cluster [Ag5{S2P(O(i)Pr)2}4]n(PF6)n, , is a monomeric unit within a coordination polymer formed through the reaction between [Ag(CH3CN)4]PF6 and the dithiophosphate ligand, [S2P(O(i)Pr)2](-), used in a M : L molar ratio of 5 : 4. All other clusters formed in the study are discrete units with encapsulated anions within the metal framework. The clusters [Ag8(X){S2P(O(i)Pr)2}6](PF6) (X = F, , Cl, , Br, ) are all cationic and contain monoanionic halogens. The related cluster [Ag8(H/D){S2P(O(i)Pr)2}6](PF6) contains either a hydride or a deuteride ion, and , respectively. The cluster [Ag8(S){S2P(O(i)Pr)2}6], , is neutral due to the di-anionic nature of the encapsulated sulfide anion. Clusters were all formed by reacting [Ag(CH3CN)4]PF6 and [S2P(O(i)Pr)2](-) in a M : L molar ratio of 8 : 6 and stirring for 1 h in THF; thereafter the respective anions (one equiv.) were added in situ. The cluster [Ag10(I)4{S2P(O(i)Pr)2}6], , is also neutral due to the charge balancing of the additional metal and halogen. In this case the M : L : X molar ratio was 10 : 6 : 4. All new clusters were characterized by (1)H and (31)P NMR, and elemental analysis, and , , were characterized by single crystal X-ray diffraction. |
| Databáze: | OpenAIRE |
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