The new energetic material ammonium dinitramide and its thermal decomposition

Autor:	A. Pfeil, T. Keicher, H. Krause, S. Löbbecke
Přispěvatelé:	Publica
Rok vydání:	1997
Předmět:	Hydrogen Inorganic chemistry Thermal decomposition chemistry.chemical_element General Chemistry Condensed Matter Physics Ammonium dinitramide Energetic material Dissociation (chemistry) chemistry.chemical_compound Decomposition pathway chemistry Thermal General Materials Science
Zdroj:	Solid State Ionics. :945-951
ISSN:	0167-2738
Popis:	The new energetic material ammonium dinitramide (ADN), NH 4 N(NO 2 ) 2 , has been investigated with regard to its thermal properties and decomposition behaviour. Thermal decomposition of ADN is observed after complete melting at 91.5 °C. The main decomposition pathway is based on the formation of NH 4 NO 3 and N 2 O followed by the thermal decomposition of NH 4 NO 3 to N 2 O and H 2 O at higher temperatures. Side reactions forming NO 2 , NO, NH 3 , N 2 and O 2 are described and a mechanism for the acid-catalyzed decomposition of hydrogen dinitramide, dissociation product of ADN, is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8edfff1ebb6ad66ff05efc586116585c https://doi.org/10.1016/s0167-2738(97)00215-4 Zobrazit plný text záznamu Full Text from ScienceDirect