Recent developments in the chemistry of organic perfluoro hypofluorites

Autor:	Walter Navarrini, Venturini Francesco, Maurizio Sansotera
Rok vydání:	2013
Předmět:	Inorganic Chemistry chemistry.chemical_compound Monomer Organic reaction Chemistry Organic Chemistry Electrophile Environmental Chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Fluorine Chemistry. 155:2-20
ISSN:	0022-1139
DOI:	10.1016/j.jfluchem.2013.07.005
Popis:	Recent findings in the synthesis of perfluoro-hypofluorites, their reactivity and their use in the preparation of important perfluoro monomers are herein summarized and analyzed. The experimental conditions to induce free radical or electrophilic reactivity as well as their use as initiation system in the oxidation and oxypolimerization of fluorinated olefins are also presented. Particular emphasis is dedicated to safety issues since organic hypofluorites have the tendency to self-decompose forming gaseous compounds.The hypofluorites considered in this review are: CF 3 OF, CF 2 (OF) 2 , CF 3 CF 2 OCF 2 OF, CF 3 OCF 2 CF 2 OCF 2 OF, CF 3 O(CF 2 O) n CF 2 OF, CF 3 OCF 2 CF 2 OF, (CF 3 ) 2 CFOF (CF 3 ) 3 COF, FS(O) 2 CF 2 CF 2 OF, CF 3 OCF 2 CF 2 CF 2 OF, cyclo-(CF 2 OCF 2 OCF)-CF 2 OF, (CF 3 ) 2 N-CF 2 OF.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8ececcdf127e7f1b2de500cc12673d8a https://doi.org/10.1016/j.jfluchem.2013.07.005 Zobrazit plný text záznamu Full Text from ScienceDirect