Evaluation of Surface Contamination by Noncontact Capacitance Method under UV Irradiation

Autor: Motohiro Kohno, Shin Yokoyama, Toshikazu Kitajima, Sadao Hirae
Rok vydání: 2002
Předmět:
Zdroj: Extended Abstracts of the 2002 International Conference on Solid State Devices and Materials.
Popis: In this study, we discuss a new method to evaluate surface contamination on oxidized silicon using noncontact capacitance-voltage measurement under UV irradiation. The UV light of wavelengths ranging from 240 nm to 290 nm generates a negative charge on the SiO2 surface without generating a positive charge and damage in SiO2. Their light wavelength dependence indicates that the photoexcited electrons are injected from Si into SiO2 and subsequently trapped at the SiO2 surface. The UV-induced charge increases when the wafer is stored in the plastic wafer box after the oxidation. From the Fourier transform infrared attenuated total reflection (FTIR-ATR) measurement, it is found that storage time dependence of the adsorbed organic contaminants (CH2 and CH3 groups) increases with the UV-induced charge. Furthermore, the Arrhenius plot of the UV-induced charge suggests that the adsorbed contaminant is bound on the surface with the hydrogen bond.
Databáze: OpenAIRE