Synthesis and Reactivity of an Early-Transition-Metal Alkynyl Cubane Mn4 C4 Cluster
| Autor: | Serhiy Demeshko, Uttam Chakraborty, Axel Jacobi von Wangelin, Franc Meyer |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry chemistry.chemical_element General Medicine General Chemistry Manganese 010402 general chemistry 01 natural sciences Catalysis 3. Good health 0104 chemical sciences Coordination complex Metal Crystallography chemistry.chemical_compound chemistry Transition metal Cubane visual_art visual_art.visual_art_medium Cluster (physics) Reactivity (chemistry) Metal clusters |
| Zdroj: | Angewandte Chemie International Edition. 58:3466-3470 |
| ISSN: | 1433-7851 |
| Popis: | While the coordination chemistry of monometallic complexes and the surface properties of extended metal particles are well understood, the control of metal nanocluster formation has remained challenging. The isolation of discrete metal clusters provides an especially rare snapshot at the nanoscale of cluster growth. The synthesis and full characterization of the first early-transition-metal alkynyl cubane and the first μ3 -alkynyl Mn3 motif are reported. |
| Databáze: | OpenAIRE |
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