High-Valent d7 NiIII versus d8 CuIII Oxidants in PCET

Autor: Aidan R. McDonald, Duenpen Unjaroen, Daniel N. Nelis, Brendan Twamley, Paolo Pirovano, Erik R. Farquhar, Robert Gericke, Marta Lovisari, Prasenjit Mondal
Rok vydání: 2019
Předmět:
Zdroj: Inorganic Chemistry
ISSN: 1520-510X
0020-1669
DOI: 10.1021/acs.inorgchem.9b03101
Popis: Oxygenases have been postulated to utilize d4 FeIV and d8 CuIII oxidants in proton-coupled electron transfer (PCET) hydrocarbon oxidation. In order to explore the influence the metal ion and d-elec...
Databáze: OpenAIRE