High-Valent d7 NiIII versus d8 CuIII Oxidants in PCET
Autor: | Aidan R. McDonald, Duenpen Unjaroen, Daniel N. Nelis, Brendan Twamley, Paolo Pirovano, Erik R. Farquhar, Robert Gericke, Marta Lovisari, Prasenjit Mondal |
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Rok vydání: | 2019 |
Předmět: | |
Zdroj: | Inorganic Chemistry |
ISSN: | 1520-510X 0020-1669 |
DOI: | 10.1021/acs.inorgchem.9b03101 |
Popis: | Oxygenases have been postulated to utilize d4 FeIV and d8 CuIII oxidants in proton-coupled electron transfer (PCET) hydrocarbon oxidation. In order to explore the influence the metal ion and d-elec... |
Databáze: | OpenAIRE |
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