Dual removal and selective recovery of phosphate and an organophosphorus pesticide from water by a Zr-based metal-organic framework
| Autor: | Carmen R. Maldonado, L. González, Francisco J. Carmona, Elisa Barea, Jorge A. R. Navarro, Natalia M. Padial |
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| Rok vydání: | 2021 |
| Předmět: |
Polymers and Plastics
Hydrogen Inorganic chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences Catalysis Biomaterials chemistry.chemical_compound Colloid and Surface Chemistry Adsorption Desorption Water decontamination Materials Chemistry Phosphorus circular economy Eutrophication 021001 nanoscience & nanotechnology Phosphate Organophosphates 6. Clean water 0104 chemical sciences Electronic Optical and Magnetic Materials chemistry 13. Climate action Pyrene Carbonate Metal-organic framework 0210 nano-technology Fenamiphos |
| Zdroj: | Materials Today Chemistry Digibug. Repositorio Institucional de la Universidad de Granada instname |
| ISSN: | 2468-5194 |
| Popis: | The authors express their thanks for the financial support provided by the Marie Sklodowska-Curie Individual Fellowships (H2020-MSCA-IF-2019-EF-ST-888972-PSustMOF, F.J.C.; H2020-MSCA-IF-2016-GF-749359-EnanSET, N.M.P.) within the European Union H2020 programme and EU FEDER. MINECO (CTQ2017-84692-R, PID2020-113608RB-I00, PEJ2018-004022-A), Universidad de Granada (Plan Propio de Investigacion and Programa Operativo FEDER Andalucia 2014-2020: B-FQM-364-UGR18), Junta de Andalucia (P18-RT-612) and 2020 Post-doctoral Junior Leadere-Retaining Fellowship, la Caixa Foundation (ID 100010434 and fellowship code LCF/BQ/PR20/11770014, N.M.P.) are also acknowledged for funding. Funding for open access charge: Universidad de Granada / CBUA. Zr-based metal-organic framework [Zr6(m3-O)4(m3-OH)4(OH)4(H2O)4(1,3,6,8-tetrakis(p-benzoate)pyrene) 2] (NU-1000) has been successfully used to remove phosphate and fenamiphos (an organophosphorus pesticide) from water solutions. In order to approach practical conditions, these studies have been performed under dynamic conditions and in the presence of relevant interferences, such as hydrogen carbonate. The results show that NU-1000 is able to adsorb 0.19 mol/mol of phosphate, reaching a plateau after 20 min, while 0.89 mol/mol fenamiphos is captured after 120 min. Afterward, a three-step strategy has been designed, allowing quantitative recovery of both phosphate anions and fenamiphos, separately, and ulterior adsorbent regeneration. Noteworthy, after this treatment, NU-1000 maintains a good performance toward the dual removal and selective desorption of phosphate and fenamiphos for at least two additional cycles. Marie Sklodowska-Curie Individual Fellowships within the European Union H2020 programme H2020-MSCA-IF-2019-EF-ST-888972-PSustMOF H2020-MSCA-IF-2016-GF-749359-EnanSET European Commission MINECO CTQ2017-84692-R PID2020-113608RB-I00 PEJ2018-004022-A Universidad de Granada (Plan Propio de Investigacion and Programa Operativo FEDER Andalucia 2014-2020) B-FQM-364-UGR18 Junta de Andalucia P18-RT-612 2020 Post-doctoral Junior Leadere-Retaining Fellowship, la Caixa Foundation 100010434 LCF/BQ/PR20/11770014 Universidad de Granada / CBUA |
| Databáze: | OpenAIRE |
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