Novel Removal of Diazinon Pesticide by Adsorption and Photocatalytic Degradation of Visible Light-Driven Fe-TiO2/Bent-Fe Photocatalyst
Autor: | Pham Van Quan, Minh Ngoc Ha, Huong Do Thi Viet, Nguyen Thi Hanh, Nguyen Thi Thanh Truc, Nguyen Minh Phuong, Ngoc Chau Chu, Doan Van Thuan, Nguyen Thi Minh Thu |
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Jazyk: | angličtina |
Rok vydání: | 2019 |
Předmět: |
Diazinon
Article Subject Dopant Chemistry 02 engineering and technology General Chemistry Pesticide 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences lcsh:Chemistry chemistry.chemical_compound Adsorption lcsh:QD1-999 Bentonite Photocatalysis Point of zero charge 0210 nano-technology Nuclear chemistry Visible spectrum |
Zdroj: | Journal of Chemistry, Vol 2019 (2019) |
ISSN: | 2090-9071 2090-9063 |
Popis: | In the study, Fe was used as a dopant to enhance photocatalytic activity of TiO2. Then, the Fe-doped TiO2 was deposited on bentonite, which was pillared by Fe. The synthesized materials were characterized by SEM, XRD, UV-Vis, BET, and point of zero charge (pHPZC). Then, the synthesized materials were used for diazinon removal under both dark and visible light conditions to investigate adsorption and photocatalytic degradation abilities of the synthesized materials. The maximum diazinon adsorption capacity of the synthesized Fe-TiO2/Bent-Fe was 27.03 mg/g. The obtained results indicated that the Fe-TiO2/Bent-Fe exhibited high photocatalytic degradation activity for removal of diazinon even under visible light. The diazinon removal experiments were also conducted using different photocatalyst dosages, under different pH and light sources to figure the optimal conditions for removal processes. The obtained results indicated that optimal photocatalyst dosage and pH were 0.5 g/L and 4.5, respectively. Finally, the natural light generated from solar could be suitable used for diazinon removal by the synthesized Fe-TiO2/Bent-Fe. |
Databáze: | OpenAIRE |
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