Synthesis of Prussian blue-embedded porous polymer for detection and removal of Cs ions
| Autor: | Karl R. Whittle, Mark D. Ogden, Sarah E. Pepper, Ho Namgung, Laurence M. Harwood, Geunseok Jang, Taek Seung Lee, Jongho Kim, Young Jin Gwon |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Detection limit Prussian blue Materials science Polymers and Plastics Coordination polymer Organic Chemistry Inorganic chemistry 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence 0104 chemical sciences Ion chemistry.chemical_compound Adsorption chemistry Materials Chemistry Particle 0210 nano-technology |
| Zdroj: | POLYMER |
| ISSN: | 0032-3861 |
| Popis: | A Prussian blue (PB)-embedded coordination polymer (COP) was prepd. by simple incorporation of PB into a COP composed of 1,1,2,2-tetrakis(4-carboxyphenyl)ethane and the Zn ion during the synthesis of COP. The PB-COP was prepd. as micro-sized particles with green emission (490 nm) from the strongly fluorescent tetraphenylethene group in the solid state through aggregation-induced emission. The PB-COP showed particle shape with sizes ranging from 1 to 6 μm. As the PB in PB-COP efficiently adsorbed Cs ions, the microstructure of PB-COP was degraded to smaller particles, along with a concomitant decrease in the green fluorescence of the PB-COP. Such a decrease in the green emission of PB-COP was used as a signal for the presence of Cs ions, in which the limit of detection for Cs ions was found to be 73.8 ppb. The hybridized material of the PB-COP can be used as both an efficient adsorbent and a sensor for Cs ions, achieving simultaneous removal and detection. |
| Databáze: | OpenAIRE |
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