Synthesis of new saccharide azacrown cryptands
| Autor: | Stanislaw Porwanski, Alain Marsura, Michalina Pintal, Florence Charbonniere-Dumarcay |
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| Přispěvatelé: | Łódź University of Technology, Structure et Réactivité des Systèmes Moléculaires Complexes (SRSMC), Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC) |
| Rok vydání: | 2015 |
| Předmět: |
Azides
Aza Compounds Cryptands Magnetic Resonance Spectroscopy Molecular Structure Chemistry Organic Chemistry Cryptand Saccharides General Medicine Nuclear magnetic resonance spectroscopy Biochemistry Combinatorial chemistry Coupling reaction Analytical Chemistry Azacrown ethers Polysaccharides Crown Ethers Staudinger-aza-Wittig reaction [CHIM]Chemical Sciences Molecule Organic chemistry |
| Zdroj: | Carbohydrate Research Carbohydrate Research, Elsevier, 2015, 414, pp.51-59. ⟨10.1016/j.carres.2015.07.007⟩ |
| ISSN: | 0008-6215 |
| DOI: | 10.1016/j.carres.2015.07.007 |
| Popis: | International audience; New cryptands including bis-azacrown and saccharidic moieties in their structure were prepared in several steps by applying Staudinger-aza-Wittig reaction (SAW). Syntheses have been started from cheap, easily available commercial compounds such as D-glucose, D-cellobiose and D-lactose subsequently transformed into their derivatives in fairly good yields (60-65%) and suitable to give desired final cryptands by direct SAW coupling reactions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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