Effect of entanglements in the microstructure of cured NR/SBR blends prepared by solution and mixing in a two-roll mill
| Autor: | M. A. Mansilla, Antonio González-Jiménez, Miguel A. López-Manchado, Juan López Valentín, Angel J. Marzocca |
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| Rok vydání: | 2016 |
| Předmět: |
Styrene-butadiene
Materials science Polymers and Plastics Ciencias Físicas RUBBER BLEND Sulfenamide General Physics and Astronomy 02 engineering and technology SWELLING Otras Ciencias Físicas 010402 general chemistry Elastomer 01 natural sciences law.invention chemistry.chemical_compound Natural rubber law Phase (matter) Materials Chemistry Composite material ENTANGLEMENT Organic Chemistry NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY Vulcanization 021001 nanoscience & nanotechnology Microstructure 0104 chemical sciences chemistry Compounding visual_art visual_art.visual_art_medium 0210 nano-technology CIENCIAS NATURALES Y EXACTAS |
| Zdroj: | European Polymer Journal. 81:365-375 |
| ISSN: | 0014-3057 |
| DOI: | 10.1016/j.eurpolymj.2016.06.023 |
| Popis: | The influence of preparation methodology of vulcanized elastomeric blends of natural rubber (NR) and styrene butadiene rubber (SBR) on the phase morphology and network structure has been studied. Two different compounding methodologies have been applied: (i) mechanical mixing in a two-roll mill and (ii) blending in solution, by dissolving the elastomers in an appropriated solvent. Samples with different NR/SBR ratios were vulcanized by using a conventional cure system based on sulfur and TBBS (n-t-butyl-2-benzothiazole sulfenamide) as accelerator. The phase distribution of rubber matrices in the blends was investigated by transmission electron microscopy (TEM), identifying differences in the compounds according to the preparation method. Weak residual dipolar couplings caused by the existence of cross-links and topological constraints in vulcanized samples were characterized by using proton multiple-quantum (MQ) NMR spectroscopy. The structural results obtained by NMR and equilibrium swelling experiments were compared and complemented with viscosity measurements. It was found that the preparation method has a strong influence on the phase morphology of blends and the molecular network structure of each rubber phase, with an important variation in the entanglements contribution, which is more pronounced when the prepared blends are richer in NR. Fil: Mansilla, Marcela Angela. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Valentín, J. L.. Consejo Superior de Investigaciones Cientificas; España Fil: López Manchado, M. A.. Consejo Superior de Investigaciones Cientificas; España Fil: González Jiménez, A.. Consejo Superior de Investigaciones Cientificas; España Fil: Marzocca, Angel José. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina |
| Databáze: | OpenAIRE |
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