The Use of UiO-Type MOFs in Vapour Phase Soai Reactions

Autor:	Carlo Buono, Andrea Lazzarini, Gurpreet Kaur, Giuesppe rotunno, Mohamed Amedjkouh
Rok vydání:	2020
Předmět:	Reaction rate Autocatalysis Materials science Phase (matter) Enantioselective synthesis Physical chemistry Substrate (chemistry) Soai reaction Enantiomeric excess
Popis:	We report a novel vapour phase procedure to perform the Soai reaction in an absolute asymmetric synthesis fashion: the substrate is confined in the pores of the UiO-type MOFs, and vapour phase reactions with Zn(i-Pr)2 are performed in a sealed environment, Different MOFs lead to different outcomes in terms of enantiomeric excess, handedness of the product and reaction rate. This is one of the first examples of absolute asymmetric synthesis performed inside a MOF.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8d32d655c216a10d628abca9e0fdf330 https://doi.org/10.26434/chemrxiv.13503369 Zobrazit plný text záznamu