Siloxane-Based Main-Chain Poly(ionic liquid)s via a Debus–Radziszewski Reaction
| Autor: | Manuel Reiter, Miriam M. Unterlass, Atefeh Khorsand Kheirabad, Jiayin Yuan |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
02 engineering and technology General Medicine 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Siloxanes Precursors Membranes Mixtures Polymers 0104 chemical sciences chemistry.chemical_compound chemistry Chain (algebraic topology) Siloxane ddc:540 Polymer chemistry Ionic liquid 0210 nano-technology |
| Zdroj: | ACS Polymers Au. 2:80-87 |
| ISSN: | 2694-2453 |
| DOI: | 10.1021/acspolymersau.1c00029 |
| Popis: | Herein, we synthesized a series of siloxane-based poly(ionic liquid)s (PILs) with imidazolium-type species in the main chain via the multicomponent Debus–Radziszewski reaction. We employed oligodimethylsiloxane diamine precursors to integrate flexible spacers in the polymer backbone and ultimately succeeded in obtaining main-chain PILs with low glass transition temperatures (Tgs) in the range of −40 to −18 °C. Such PILs were combined with conventional hydrophobic vinylimidazolium-based PILs for the fabrication of porous membranes via interpolyelectrolyte complexation with poly(acrylic acid), which leads to enhanced mechanical performance in the tensile testing measurements. This study will enrich the structure library of main-chain PILs and open up more opportunities for potential industrial applications of porous imidazolium-based membranes. published |
| Databáze: | OpenAIRE |
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