Mid-infrared emissivity of crystalline silicon solar cells

Autor: D. Alonso Alvarez, Nicholas J. Ekins-Daukes, Christos N. Markides, Alexander Mellor, L. Ferre Llin, Daniel Chemisana, Alberto Riverola, Douglas J. Paul, I. Guarracino
Přispěvatelé: Commission of the European Communities, Engineering & Physical Science Research Council (EPSRC), Engineering & Physical Science Research Council (E
Rok vydání: 2018
Předmět:
Zdroj: Repositorio Abierto de la UdL
Universitad de Lleida
Recercat. Dipósit de la Recerca de Catalunya
instname
ISSN: 0927-0248
DOI: 10.1016/j.solmat.2017.10.002
Popis: The thermal emissivity of crystalline silicon photovoltaic (PV) solar cells plays a role in determining the operating temperature of a solar cell. To elucidate the physical origin of thermal emissivity, we have made an experimental measurement of the full radiative spectrum of the crystalline silicon (c-Si) solar cell, which includes both absorption in the ultraviolet to near-infrared range and emission in the mid-infrared. Using optical modelling, we have identified the origin of radiative emissivity in both encapsulated and unencapsulated solar cells. We find that both encapsulated and unencapsulated c-Si solar cells are good radiative emitters but achieve this through different effects. The emissivity of an unencapsulated c-Si solar cell is determined to be 75% in the MIR range, and is dominated by free-carrier emission in the highly doped emitter and back surface field layers; both effects are greatly augmented through the enhanced optical outcoupling arising from the front surface texture. An encapsulated glass-covered cell has an average emissivity around 90% on the MIR, and dips to 70% at 10 µm and is dominated by the emissivity of the cover glass. These findings serve to illustrate the opportunity for optimising the emissivity of c-Si based collectors, either in conventional c-Si PV modules where high emissivity and low-temperature operation is desirable, or in hybrid PV-thermal collectors where low emissivity enables a higher thermal output to be achieved. This research was supported by the 'Ministerio de Economía y Competitividad' of Spain (grants ENE2013-48325-R, BES-2014-069596 and EEBB-I-16-11459) and the by the UK Engineering and Physical Science Research Council (EPSRC) [grant number EP/M025012/1]. A. Mellor was supported by the European Commission through Marie Sklodowska Curie International Fellowship, Grant No. DLV-657359. Re fl ection and Transmission measurements were performed by Dr. Volker Kübler in the Micro-structured Surfaces Group of Fraunhofer- ISE, Freiburg, Germany.
Databáze: OpenAIRE