A Simple Method for Controlling Dendritic Architecture and Diversity: A Parallel Monomer Combination Approach

Autor:	Adam W. Freeman, Jean M. J. Fréchet, Lysander A. J. Chrisstoffels
Rok vydání:	2000
Předmět:	chemistry.chemical_compound Monomer chemistry Benzyl ether Dendrimer Organic Chemistry Dendritic architecture Nanotechnology Combinatorial chemistry Macromolecule Simple (philosophy)
Zdroj:	The Journal of Organic Chemistry. 65:7612-7617
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo005592i
Popis:	A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers that possess a predetermined number and arrangement of "internal" functional moieties. This methodology is applied for the preparation of a novel family of poly(benzyl ether) dendrimers possessing 1-15 "internal" allyloxy groups, which are displayed in a highly controlled, layer-specific, generational manner.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8cfa97dfd25e923ece26d42e9d242380 https://doi.org/10.1021/jo005592i Zobrazit plný text záznamu