VARIABLE PHOTON ENERGY PHOTOELECTRON-SPECTROSCOPY OF MO-2(O2CCF3)(4)
| Autor: | Martin P. Payne, Catherine M. Redfern, Jennifer C. Green, Glyn Cooper, John G. Brennan |
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| Rok vydání: | 2016 |
| Předmět: |
Radiation
chemistry.chemical_element Photoionization Photon energy Condensed Matter Physics Branching (polymer chemistry) Oxygen Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Metal chemistry X-ray photoelectron spectroscopy Comparable size visual_art Ionization visual_art.visual_art_medium Physical and Theoretical Chemistry Atomic physics Spectroscopy |
| Popis: | Relative partial photoionization cross sections, branching ratios and β measurements are reported for Mo2(O2CCF3)4 over the photon energy range 20 to 70 eV. The metal based δ and σ + π ionizations are strongly enhanced over the photon energy range 36–65 eV. The comparable size of the resonance in the two metal bands suggests similar d character for the associated MO. A smaller resonance is also found in the oxygen localized ionization bands. An additional resonance is identified for the δ band at 24 eV which is accompanied by a change in β. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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