Inexpensive organic dyes-sensitized zinc oxide nanoparticles photoanode for solar cells devices
| Autor: | Nabil Kh. Shurrab, Ahmed Issa, Naji Al Dahoudi, Hamdiya Zayed, Jihad Asad, Samy K. Shaat, H. Musleh |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Photoluminescence Inorganic chemistry Nanoparticle chemistry.chemical_element Nanotechnology 02 engineering and technology Zinc 010402 general chemistry 01 natural sciences eosin DSSCs transient open circuit photovoltage decay electron recombination Spectroscopy defects lifetime Renewable Energy Sustainability and the Environment 021001 nanoscience & nanotechnology Atomic and Molecular Physics and Optics 0104 chemical sciences Dye-sensitized solar cell chemistry Transmission electron microscopy X-ray crystallography solar cells clean renewable energy photoluminescence traps 0210 nano-technology Luminescence |
| Popis: | Zinc oxide nanoparticles (ZnO NPs) were synthesized using a hydrothermal route. The prepared ZnO NPs were characterized by x-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), UV–vis spectroscopy, and photoluminescence (PL) spectroscopy. The XRD patterns confirmed the standard hexagonal wurtzite structure of ZnO NPs, and the calculated value of the average particle size was 23.34 nm. HR-TEM micrographs of ZnO NPs showed semispherical particle morphologies and their sizes lie between 10 and 40 nm. The estimated average size distribution of ZnO NPs was 21.35 6.01 nm. UV–vis spectrum of ZnO NPs revealed the highest absorption band at 360.5 nm, and the Eg was 3.70 0.01 eV. The PL spectrum emission was deconvoluted by eight peaks into two regions [near-ultraviolet (NUV) and visible that caused from the defects]. Two groups of dye-sensitized solar cells (DSSCs) thin film devices based on ZnO NPs were sensitized in different concentration solutions of 0.1, 0.32, and 0.5 mM of eosin B (EB) and eosin Y (EY) dyes. The sensitized DSSCs device with 0.32-mM dye of EY displayed higher efficiency and its performance parameters are much better among all other fabricated DSSCs devices. The short current density (Jsc) increased from 1.59 to 4:97 mA∕cm2 and the Voc enhanced from 0.36 to 0.46 V. The conversion efficiency from light to electricity showed a significant improvement from 0.29% to 0.94%. The transient open circuit photovoltage decay (TOCPVD) was measured to estimate the apparent electron lifetime or response time (τn) or the electron recombination rate (krec), using the double exponential function for first time to fit the experiment data of TOCPVD. The results revealed that the EY dye can be used as an efficient and an inexpensive dye for DSSCs. This research activity carried out between Gaza and Cairo-Egypt was financially supported by Qatar Charity IBHATH Project grant funded by the Gulf Cooperation Council for the Reconstruction of Gaza through the Islamic Development Bank. Zinc oxide nanoparticles (ZnO NPs) were synthesized using a hydrothermal route. The prepared ZnO NPs were characterized by x-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), UV–vis spectroscopy, and photoluminescence (PL) spectroscopy. The XRD patterns confirmed the standard hexagonal wurtzite structure of ZnO NPs, and the calculated value of the average particle size was 23.34 nm. HR-TEM micrographs of ZnO NPs showed semispherical particle morphologies and their sizes lie between 10 and 40 nm. The estimated average size distribution of ZnO NPs was 21.35 6.01 nm. UV–vis spectrum of ZnO NPs revealed the highest absorption band at 360.5 nm, and the Eg was 3.70 0.01 eV. The PL spectrum emission was deconvoluted by eight peaks into two regions [near-ultraviolet (NUV) and visible that caused from the defects]. Two groups of dye-sensitized solar cells (DSSCs) thin film devices based on ZnO NPs were sensitized in different concentration solutions of 0.1, 0.32, and 0.5 mM of eosin B (EB) and eosin Y (EY) dyes. The sensitized DSSCs device with 0.32-mM dye of EY displayed higher efficiency and its performance parameters are much better among all other fabricated DSSCs devices. The short current density (Jsc) increased from 1.59 to 4:97 mA∕cm2 and the Voc enhanced from 0.36 to 0.46 V. The conversion efficiency from light to electricity showed a significant improvement from 0.29% to 0.94%. The transient open circuit photovoltage decay (TOCPVD) was measured to estimate the apparent electron lifetime or response time (τn) or the electron recombination rate (krec), using the double exponential function for first time to fit the experiment data of TOCPVD. The results revealed that the EY dye can be used as an efficient and an inexpensive dye for DSSCs. |
| Databáze: | OpenAIRE |
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