Tracking Lithium Ions via Widefield Fluorescence Microscopy for Battery Diagnostics
Autor: | Andrew C. Cavell, Randall H. Goldsmith, Kyle A. Desrochers, Tyler Derus, Michael Foy, Alvaro Masias, Kassandra A. Knapper, Sunil P. Upadhyay, Daniel A. Hinton, Nicolas A. Padilla, Sharla L. Wood, Morgan T. Rea, Nathanael H. Hunter |
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Rok vydání: | 2017 |
Předmět: |
Fluid Flow and Transfer Processes
Battery (electricity) Fluorophore Process Chemistry and Technology chemistry.chemical_element Bioengineering Nanotechnology 02 engineering and technology Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence Lithium battery 0104 chemical sciences Ion chemistry.chemical_compound chemistry Fluorescence microscope Lithium 0210 nano-technology Instrumentation |
Zdroj: | ACS sensors. 2(7) |
ISSN: | 2379-3694 |
Popis: | Direct tracking of lithium ions with time and spatial resolution can provide an important diagnostic tool for understanding mechanisms in lithium ion batteries. A fluorescent indicator of lithium ions, 2-(2-hydroxyphenyl)naphthoxazole, was synthesized and used for real-time tracking of lithium ions via widefield fluorescence microscopy. The fluorophore can be excited with visible light and was shown to enable quantitative determination of the lithium ion diffusion constant in a microfluidic model system for a plasticized polymer electrolyte lithium battery. The use of widefield fluorescence microscopy for in situ tracking of lithium ions in batteries is discussed. |
Databáze: | OpenAIRE |
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