Efficient modular phosphorus-containing ligands for stereoselective catalysis
| Autor: | Andrés Romero-Navarro, Alicia Martínez-Carrión, Nuria Llorente, Alba Martínez-Bascuñana, José Luis Núñez-Rico, Lucas Carreras, Anton Vidal-Ferran, Ester Iniesta, Héctor Fernández-Pérez |
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| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Chemistry General Chemical Engineering Phosphorus Asymmetric hydrogenation Enantioselective synthesis Supramolecular chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Catalysis Nucleophilic substitution Stereoselectivity Hydroformylation |
| Zdroj: | RECERCAT (Dipòsit de la Recerca de Catalunya) Recercat. Dipósit de la Recerca de Catalunya instname |
| Popis: | Over several years, our research team has contributed to ligand design for metal-catalyzed stereoselective transformations. This has been achieved with the synthesis and application to organic transformations of interest of an array of structurally diverse P-containing ligands. These range from highly modular enantiopure phosphine–phosphite ligands to supramolecularly regulated enantioselective phosphorus-based catalysts. Our research in supramolecular interactions has also led to the discovery of an unprecedented halogen-bonded rhodium-catalyst. |
| Databáze: | OpenAIRE |
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