Preparation and characterisation of thiol functionalised p-tert-butylcalix[4]arene-embedded polymer inclusion membranes: performance and selectivity
| Autor: | Esengul Kir, Tugba Sardohan-Koseoglu, Mehmet Soner Engin, Serkan Sayin, Seydahmet Cay |
|---|---|
| Přispěvatelé: | Belirlenecek |
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Health
Toxicology and Mutagenesis trace metals Soil Science surface characterisation 010501 environmental sciences 01 natural sciences Analytical Chemistry chemistry.chemical_compound Calixarene Polymer chemistry Environmental Chemistry ion transportation Waste Management and Disposal 0105 earth and related environmental sciences Water Science and Technology chemistry.chemical_classification 010401 analytical chemistry Public Health Environmental and Occupational Health Polymer Pollution Ion transportation 0104 chemical sciences polymer inclusion membrane Membrane chemistry Thiourea Thiol Selectivity Derivative (chemistry) |
| Popis: | Sayin, Serkan/0000-0003-0518-3208; Kir, Esengul/0000-0002-6641-3444 WOS: 000471447100001 Here in we report the syntheses of the thiol functionalised p-tert-butylcalix[4]arene from the reaction of p-tert-butylcalix[4]arene-dialkylbromide derivative with thiourea. The structure of the thiol functionalised p-tert-butylcalix[4]arene was determined by using (HNMR)-H-1, (CNMR)-C-13 and elemental analysis techniques. Furthermore, the thiol functionalised p-tert-butylcalix[4]arene, cellulose triacetate (CTA) and 2-nitrophenyl octyl ether (o-NPPE) in dichloromethane were used to make a new calixarene-embedded polymer inclusion membrane (Bu-t-C@PIM). The surface and structure morphology of Bu-t-C@PIM was detected using thermogravimetric analysis, elemental analysis techniques and scanning electron microscopy. The affinity (the percentage of metal ion transferred from the source solution) of a PIM towards a range of divalent cations was found to follow the order Pb2+ > Zn2+ > Ni2+ > Cu2+ > Cd2+ > Co2+. The results also indicated that the transport efficiency of Bu-t-C@PIM was repeatable and may be beneficial in the development of a simplistic and highly influential trace metal recovery method from aqueous solution. Scientific and Technological Research Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [215Z570] This work was supported by the Scientific and Technological Research Council of Turkey [215Z570]. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|