Selective cation and anion guest binding in host selenazamacrocycles

Autor:	Upali Patel, Colin D. McMillen, Mohammed A. Abbas, Julia L. Brumaghim
Rok vydání:	2018
Předmět:	Inorganic Chemistry Reaction conditions 010405 organic chemistry Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Ion
Zdroj:	Dalton Transactions. 47:12066-12070
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c8dt02110d
Popis:	We report selenazamacrocycle hosts that are the first system to change guest binding affinity from cation to anion depending upon macrocycle oxidation/reduction. Selective cation (Fe2+) or anion (BF4-) binding occurs with both ions present and under identical reaction conditions. We also report the first macrocyclic complex with a Fe-Se bond.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8b660adc3c1d0d6bd85a2296b8bb516b https://doi.org/10.1039/c8dt02110d Zobrazit plný text záznamu