Comparison of topotactic fluorination methods for complex oxide films

Autor: Amber K. Choquette, Amanda Huon, Dmitri Barbash, Steven J. May, Eun Ju Moon, S. Z. Kulesa
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: APL Materials, Vol 3, Iss 6, Pp 062511-062511-7 (2015)
Popis: We have investigated the synthesis of SrFeO3−αFγ (α and γ ≤ 1) perovskite films using topotactic fluorination reactions utilizing poly(vinylidene fluoride) as a fluorine source. Two different fluorination methods, a spin-coating and a vapor transport approach, were performed on as-grown SrFeO2.5 films. We highlight differences in the structural, compositional, and optical properties of the oxyfluoride films obtained via the two methods, providing insight into how fluorination reactions can be used to modify electronic and optical behavior in complex oxide heterostructures.
Databáze: OpenAIRE