Synthesis of disparlure and monachalure enantiomers from 2,3-butanediacetals
| Autor: | Bożena Frąckowiak-Wojtasek, Adam Drop, Hubert Wojtasek |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
2
3-butanediacetal Stereochemistry 010402 general chemistry 01 natural sciences Full Research Paper cis-epoxide lcsh:QD241-441 lcsh:Organic chemistry Lymantria dispar 3-butanediacetal lcsh:Science (+)-monachalure biology 010405 organic chemistry Chemistry Organic Chemistry (−)-monachalure Lymantria monacha Gypsy moth biology.organism_classification 0104 chemical sciences (−)-disparlure Sex pheromone lcsh:Q Enantiomer (+)-disparlure |
| Zdroj: | Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 616-620 (2020) |
| ISSN: | 1860-5397 |
| Popis: | 2,3-Butanediacetal derivatives were used for the stereoselective synthesis of unsymmetrically substituted cis-epoxides. The procedure was applied for the preparation of both enantiomers of disparlure and monachalure, the components of the sex pheromones of the gypsy moth (Lymantria dispar) and the nun moth (Lymantria monacha) using methyl (2S,3R,5R,6R)-3-ethylsulfanylcarbonyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carboxylate as the starting material. |
| Databáze: | OpenAIRE |
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