Silica modified membrane for carbon dioxide separation from natural gas
Autor: | Yilmaz Yildirim, Alhaji Shehu Grema, Mohammed Nasir Kajama, Usman Taura, Shehu Abdulrahman |
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Přispěvatelé: | Zonguldak Bülent Ecevit Üniversitesi |
Jazyk: | angličtina |
Rok vydání: | 2018 |
Předmět: |
Dip-coating technique
Materials science business.industry single gas permeation and selectivity silica membrane 02 engineering and technology carbon dioxide separation 021001 nanoscience & nanotechnology chemistry.chemical_compound Membrane 020401 chemical engineering chemistry Chemical engineering Natural gas Carbon dioxide Silica membrane 0204 chemical engineering 0210 nano-technology business |
ISSN: | 0004-4520 |
Popis: | WOS: 000445201200005 A dip-coating technique was applied to prepare a selective membrane on a commercial ceramic mesoporous support. Single gas components used for permeance and selectivity were CH4, CO2, H-2, He, N-2, and O-2 (BOC UK) with at least 99.999 (% v/v) purity. The permeances and selectivities were obtained at room temperature and transmembrane pressure differences between 0.05 up to 5.0 barg. Gas permeation experiments showed the permeance of CO2 to be strongly influenced by surface diffusion mechanism. Single gas experiment showed linear flow dependence on the inverse square root of molecular weight at room temperature and 1.0 barg. The single gas selectivities were found to be higher than the ideal Knudsen separation mechanism. The highest CO2/CH4 selectivity value of 24.07 was obtained at 0.7 barg and room temperature. Petroleum Technology Development Fund (PTDF) Nigeria The authors gratefully acknowledge Petroleum Technology Development Fund (PTDF) Nigeria for funding this research; Centre for Process Integration and Membrane Technology, (CPIMT), School of Engineering, The Robert Gordon University, Aberdeen, United Kingdom for providing the ceramic membrane and the reactor, and School of Pharmacy & Life Sciences RGU Aberdeen for the SEM results. |
Databáze: | OpenAIRE |
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