Total Synthesis and Stereochemistry Assignment of Nucleoside Antibiotic A-94964
Autor: | Xiaofei Shao, Chang Zheng, Peng Xu, Taro Shiraishi, Tomohisa Kuzuyama, Antonio Molinaro, Alba Silipo, Biao Yu |
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Přispěvatelé: | Shao, X., Zheng, C., Xu, P., Shiraishi, T., Kuzuyama, T., Molinaro, A., Silipo, A., Yu, B. |
Jazyk: | angličtina |
Rok vydání: | 2022 |
Předmět: | |
Popis: | A collective total synthesis of eight diastereoisomers associated with NMR analysis leads to a full stereochemistry assignment of the structurally unique nucleoside antibiotic A-94964, which features an octuronic acid uridine core decorated with an α-D-mannopyranosyl residue and an α-D-N-acylglucosaminopyranosyl residue via a phosphodiester bridge. |
Databáze: | OpenAIRE |
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