Modelling an electrochemically roughened porous platinum electrode for water oxidation
| Autor: | Paul Carter, Chuan Zhao, Xunyu Lu, Alexander Weremfo, D. Brynn Hibbert |
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| Rok vydání: | 2016 |
| Předmět: |
Materials science
Inorganic chemistry Metals and Alloys Oxygen evolution chemistry.chemical_element 02 engineering and technology General Chemistry Surface finish 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Redox Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Electrode Materials Chemistry Ceramics and Composites Surface roughness 0210 nano-technology Platinum Porosity |
| Zdroj: | Chemical Communications. 52:4068-4071 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c5cc09947a |
| Popis: | Pt is usually not considered as an efficient catalyst for water oxidation. Here, we report a design-of-experiment approach for modelling the roughness of an electrochemically roughened Pt electrode for water oxidation. The results indicate significant interaction between oxidation and reduction potentials on surface roughness and the porous Pt exhibits greatly improved catalytic activity for oxygen evolution in acid which is comparable to the benchmark catalyst RuO₂. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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