Collisional removal of CD(A 2Δ and B 2Σ−) by Xe. Dependence on rotational and vibrational excitation

Autor:	Margarita Martín, Carolina Cerezo
Přispěvatelé:	Dirección General de Investigación Científica y Técnica, DGICT (España), European Commission
Rok vydání:	1998
Předmět:	Quenching Deuterium Chemistry General Physics and Astronomy Rotational–vibrational spectroscopy Physical and Theoretical Chemistry Atomic physics Quantum number Excitation
Zdroj:	Digital.CSIC. Repositorio Institucional del CSIC instname
ISSN:	0009-2614
Popis:	The collisional removal by Xe of several rovibrational levels of deuterated methylidyne in the A 2Δ and B 2Σ− states has been studied. The quenching of the CD(A 2Δ, v=0) state depends on rotational quantum number: for quantum numbers N′=4–12 the quenching rates increase from 2.7×10−11 to 4.0×10−11 cm3 molec−1 s−1, remain nearly constant for N′=12–16 and decrease to 2.3×10−11 cm3 molec−1 s−1 for N′=20. The A 2Δ and B 2Σ− states are quenched at similar rates. The quenching of both states does not depend on vibrational excitation. Financial support from Spanish DGICYT (PB96-0844-CO2-01) and the HCM Programme of the European Community (CHRX-CT94-0485) is acknowledged.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8a9305a25ecb0c36e9f98ea9e5c9cf85 https://doi.org/10.1016/s0009-2614(98)00358-3 Zobrazit plný text záznamu Full Text from ScienceDirect