Efficient Sialylation with Phenyltrifluoroacetimidates as Leaving Groups
| Autor: | Biao Yu, Sutang Cai |
|---|---|
| Rok vydání: | 2003 |
| Předmět: |
Trimethylsilyl Compounds
Glycosylation animal structures Molecular Structure Scope (project management) Chemistry Organic Chemistry General Medicine Computational biology Biochemistry N-Acetylneuraminic Acid Catalysis carbohydrates (lipids) chemistry.chemical_compound Models Chemical Acetamides embryonic structures cardiovascular system Organic chemistry Physical and Theoretical Chemistry |
| Zdroj: | Organic Letters. 5:3827-3830 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/ol0353161 |
| Popis: | [reaction: see text] Sialylation with N-phenyltrifluoroacetimidates as leaving groups and a catalytic amount of TMSOTf as promoter compares favorably with the previous protocols for direct sialylation and expand in essence the scope of the Schmidt glycosylation reaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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