An effective diphosphoramidite rhodium catalyst for selective hydroformylation of 1-octene
| Autor: | Carmela G. Arena, Dario Drommi |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Rhodium catalyst
010405 organic chemistry Chemistry Ligand Process Chemistry and Technology Chemistry (all) chemistry.chemical_element General Chemistry Homogeneous catalysis 010402 general chemistry Highly selective 01 natural sciences Diphosphoramidite Homogeneous catalysis Hydroformylation Regioselectivity Rhodium catalyst Catalysis Chemistry (all) Process Chemistry and Technology Catalysis Diphosphoramidite 0104 chemical sciences Rhodium Trigonal bipyramidal molecular geometry chemistry.chemical_compound Regioselectivity Polymer chemistry Hydroformylation 1-Octene |
| Zdroj: | Catalysis Communications. 115:36-39 |
| ISSN: | 1566-7367 |
| DOI: | 10.1016/j.catcom.2018.07.004 |
| Popis: | A very efficient and highly selective rhodium catalyst with a C2-symmetric BINOL-derived diphosphoramidite ligand for hydroformylation of 1-octene has been developed. At mild conditions (50 °C and 10 bar H2/CO) a very active rhodium catalyst has been obtained which produces over 99% of aldehydes with 98.2% n-regioselectivity. The spectroscopic characterization of the hydridorhodium catalytically active species showed that the diphosphoramidite ligand coordinates bis-equatorially in the trigonal bipyramidal rhodium complex, which coupled with its π-acceptor capacity might account for the high catalyst performance. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect